1295585-45-3

Basic information

• Product Name: 2-(4-methoxy-3-methylphenyl)hydrazono-5-methylcyclohexanone
• CAS NO: 1295585-45-3
• Molecular Weight: 260.336
• Mol File: 1295585-45-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-(4-methoxy-3-methylphenyl)hydrazono-5-methylcyclohexanone(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(4-methoxy-3-methylphenyl)hydrazono-5-methylcyclohexanone(1295585-45-3)
• EPA Substance Registry System: 2-(4-methoxy-3-methylphenyl)hydrazono-5-methylcyclohexanone(1295585-45-3)

Safety Data

• Hazardous Substances Data: 1295585-45-3(Hazardous Substances Data)

Upstream product

• 95-48-7 ortho-cresol 
• 31910-25-5 N-(4-methoxy-3-methylphenyl)acetamide 
• 2835-96-3 4-amino-2-methylphenol 
• 6971-38-6 p-nitroso-o-cresol 
• 16375-90-9 4-acetamido-2-methylphenol 
• 53535-74-3 2-(hydroxymethylidene)-5-methylcyclohexanone 
• 1185297-84-0 4-methoxy-3-methylaniline hydrochloride 

Relevant articles and documents

A novel CAN-SiO2-mediated one-pot oxidation of 1-keto-1,2,3,4-tetrahydrocarbazoles to carbazoloquinones: Efficient syntheses of murrayaquinone A and koeniginequinone A

One-pot oxidations of substituted 1-keto-1,2,3,4-tetrahydrocarbazoles (1) to carbazole-1,4-quinones (2) are efficiently carried out by CAN-SiO 2-mediated reaction. This generalized protocol was successfully extended to the synthesis of two naturally occurring carbazoloquinones: murrayaquinone A (2b) and koeniginequinone A (2g). A plausible mechanism for this novel reaction involves formation of a 9-hydroxy-2,3,4,9-tetrahydro-1H- carbazole-1-one followed by rearrangement to 1-hydroxycarbazole derivatives, which are further oxidized by cerium (IV) to carbazoloquinones.