129568-35-0

Basic information

• Product Name: Bicyclo[2.2.1]hept-5-ene-2-carboxaldehyde, 3-acetyl-, (2-endo,3-exo)- (9CI)
• Synonyms: Bicyclo[2.2.1]hept-5-ene-2-carboxaldehyde, 3-acetyl-, (2-endo,3-exo)- (9CI)
• CAS NO: 129568-35-0
• Molecular Formula: C10H12O2
• Molecular Weight: 164.20108
• Product Categories: ACETYLGROUP
• Mol File: 129568-35-0.mol
• Article Data: 3

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Bicyclo[2.2.1]hept-5-ene-2-carboxaldehyde, 3-acetyl-, (2-endo,3-exo)- (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Bicyclo[2.2.1]hept-5-ene-2-carboxaldehyde, 3-acetyl-, (2-endo,3-exo)- (9CI)(129568-35-0)
• EPA Substance Registry System: Bicyclo[2.2.1]hept-5-ene-2-carboxaldehyde, 3-acetyl-, (2-endo,3-exo)- (9CI)(129568-35-0)

Safety Data

• Hazardous Substances Data: 129568-35-0(Hazardous Substances Data)

Upstream product

• 22414-24-0 2,5-dihydro-2,5-dimethoxy-2-methylfuran 
• 534-22-5 2-methylfuran 
• 34218-22-9 1-oxo-2(Z)-penten-4-one 
• 542-92-7 cyclopenta-1,3-diene 

Relevant articles and documents

Synthesis of diacetal trioxa-cage compounds via reaction of bicyclo[2.2.1]heptenes and bicyclo[2.2.2]octenes with dimethyldioxirane

A new entry for the synthesis of diacetal trioxa-cage compounds via oxirane-induced sequential cyclization reaction of 2,3-bis-endo- diacylbicyclo[2.2.1]-5-heptenes and 2,3-bis-endo-diacylbicyclo[2.2.2]-5- octenes is reported. In the case of bicyclo[2.2.2]octenes, sequential cyclization reaction induced by iodine as electrophile failed. We have also demonstrated that dimethyldioxirane can selectively oxidize hemiacetals to give lactones with the secondary hydroxy group intact. (C) 2000 Elsevier Science Ltd.

Stereospecific total synthesis of (±)pentenomycins by flash vacuum thermolysis of substituted tricyclo[5.2.1.02,6]decenones

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