129576-13-2

Upstream product

• 129576-06-3 Trimethyl-{(R)-1-phenyl-1-[1-((S)-toluene-4-sulfinyl)-cyclopropyl]-ethoxy}-silane 
• 129576-05-2 Acetic acid (R)-1-phenyl-1-[1-((S)-toluene-4-sulfinyl)-cyclopropyl]-ethyl ester 
• 106358-73-0 (Ss)-1-(1-Hydroxy-1-phenylethyl)-1-p-toluenesulfinylcyclopropane 

Downstream Products

• 106358-77-4 (R)-(-)-4-Methyl-4-phenyl-1-p-toluenesulfenylcyclobutene 

Relevant academic research and scientific papers

Stereochemistry of Asymmetric 1,2-Rearrangements of Chiral Sulfenylcyclopropanes into Cyclobutane Derivatives. A Novel Entry to Chiral Cyclobutane Systems Using Chiral Sulfinyl Groups

Stereochemistry of 1,2-rearrangements in optically active 1-(1-hydroxyalkyl)-1-sulfenylcyclopropane derivatives was determined.Both of the enantiomers underwent smoothly a 1,2-rearrangement of carbon-carbon bonds in cyclopropanes via the mesylates with complete stereospecificity to provide chiral cyclobutane derivatives with high enantiomeric excess.