106358-77-4

Upstream product

• 50299-85-9 (R_s)-(+)-p-toluenesulfinylcyclopropane 
• 93-58-3 benzoic acid methyl ester 
• 128175-63-3 Methanesulfonic acid (R)-1-phenyl-1-[1-((S)-toluene-4-sulfinyl)-cyclopropyl]-ethyl ester 
• 128175-64-4 Methanesulfonic acid (S)-1-phenyl-1-[1-((S)-toluene-4-sulfinyl)-cyclopropyl]-ethyl ester 
• 128175-61-1 (S)-1-Benzoyl-1-p-toluenesulfinylcyclopropane 
• 128175-62-2 (S)-1-Acetyl-1-p-toluenesulfinylcyclopropane 
• 129576-06-3 Trimethyl-{(R)-1-phenyl-1-[1-((S)-toluene-4-sulfinyl)-cyclopropyl]-ethoxy}-silane 
• 129576-05-2 Acetic acid (R)-1-phenyl-1-[1-((S)-toluene-4-sulfinyl)-cyclopropyl]-ethyl ester 
• 98-86-2 acetophenone 
• 129576-13-2 (R)-1-Phenyl-1-(1-p-tolylsulfanyl-cyclopropyl)-ethanol 
• 106375-24-0 1-Methyl-4-((S)-(R)-4-methyl-4-phenyl-cyclobut-1-enesulfinyl)-benzene 

Downstream Products

• 106401-77-8 (R)-(-)-2-methyl-2-phenylcyclobutane 
• 106358-84-3 (R)-2-methyl-2-phenylsuccinic acid 
• 106358-80-9 (R)-2-Methyl-2-phenyl-4-phenylsulfanyl-cyclobutanone 

Relevant academic research and scientific papers

Stereoselective synthesis and stereospecific asymmetric 1,2-rearrangements of chiral sulfinylcyclopropane derivatives

Stereo selective synthesis of chiral sulfinylcyclopropane derivatives and stereochemistry of the asymmetric 1,2-rearrangements are described. Heating of each stereoisomeric mesylate of (Ss)-1-(1-hydroxy-1-phenylethyl)-1-p-toluenesulfinylcyclopropane, foll

Stereochemistry of Asymmetric 1,2-Rearrangements of Chiral Sulfenylcyclopropanes into Cyclobutane Derivatives. A Novel Entry to Chiral Cyclobutane Systems Using Chiral Sulfinyl Groups

Stereochemistry of 1,2-rearrangements in optically active 1-(1-hydroxyalkyl)-1-sulfenylcyclopropane derivatives was determined.Both of the enantiomers underwent smoothly a 1,2-rearrangement of carbon-carbon bonds in cyclopropanes via the mesylates with complete stereospecificity to provide chiral cyclobutane derivatives with high enantiomeric excess.