1296303-91-7Relevant academic research and scientific papers
A series of Zn(II) terpyridine complexes with enhanced two-photon-excited fluorescence for in vitro and in vivo bioimaging
Zhang, Qiong,Tian, Xiaohe,Hu, Zhangjun,Brommesson, Caroline,Wu, Jieying,Zhou, Hongping,Li, Shengli,Yang, Jiaxiang,Sun, Zhaoqi,Tian, Yupeng,Uvdal, Kajsa
, p. 7213 - 7221 (2015/09/21)
It is still a challenge to obtain two-photon excited fluorescent bioimaging probes with intense emission, high photo-stability and low cytotoxicity. In the present work, four Zn(ii)-coordinated complexes (1-4) constructed from two novel D-A and D-π-A liga
Sulfur-containing terpyridine derivatives: Synthesis, coordination properties, and adsorption on the gold surface
Romashkina,Majouga,Beloglazkina,Pichugina,Askerka,Moiseeva,Rakhimov,Zyk
, p. 2265 - 2281 (2013/10/01)
Approaches to the synthesis of organic aurophilic ligands, viz., sulfur-containing 2,2′:6′,2'-terpyridine derivatives, were developed. Complexation reactions of the terpyridine ligands having thiophenol, diaryl disulfide, and alkyl aryl sulfide fragments with Co ii, Ni ii, and Rh iii salts were studied. The structures of the coordination compounds obtained were established based on the elemental analysis data, density functional calculations, and electron spectroscopy. The structure of the complex of 4′-(4-methylsulfanyl)-2,2′:6′,2-terpyridine with Ni(BF4)2 was also established by X-ray diffraction analysis. A method was proposed for the preparation of gold nanoparticle dimeric aggregates via coordination interactions of the ligands adsorbed on the gold nanoparticle surface with transition metal ions. A degree of nanoparticle aggregation upon their reaction with solutions of complex compounds of aurophilic nitrogen-containing ligands was determined by the concentration of the solution of the complex used.
Efficient synthetic approaches to access ruthenium(II) complexes with 2-(Trimethylsilyl)ethyl- or acetyl-protected terpyridine-thiols
Wen, Hui-Min,Zhang, Dao-Bin,Zhang, Li-Yi,Shi, Lin-Xi,Chen, Zhong-Ning
experimental part, p. 1784 - 1791 (2011/06/25)
A series of thiol-functionalized terpyridines (tpy) with protective groups, such as acetyl (Ac), 2-(trimethylsilyl)ethyl (TMSE), and tert-butyl (tBu), and the corresponding ruthenium(II) complexes were synthesized in high yields. The TMSE-protected thiol-
