129634-62-4Relevant academic research and scientific papers
50. Synthesis of the Enantiomerically Enriched Macrocyclic Lactones (+)-(S)- and (-)-(R)-Phoracantholide I and (+)-(S)-Tetradecan-13-olide
Stanchev, Stephan,Hesse, Manfred
, p. 460 - 467 (1990)
Synthesis of two naturally occurring macrocyclic lactones is described. (-)-(R)-Phoracantholide I ((-)-1; Scheme 2) was synthesized by asymmetric and chemoselective reduction of the side-chain C=O group of (-)-4-(1-nitro-2-oxocyclohexyl)butan-2-one ((-)-6
