50. Synthesis of the Enantiomerically Enriched Macrocyclic Lactones (+)-(S)- and (-)-(R)-Phoracantholide I and (+)-(S)-Tetradecan-13-olide

DOI: 10.1002/hlca.19900730226

Source and publish data:

Helvetica Chimica Acta p. 460 - 467 (1990)

Update date:2022-08-04

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Authors:

Stanchev, Stephan

Hesse, Manfred

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Article abstract of DOI:10.1002/hlca.19900730226

Synthesis of two naturally occurring macrocyclic lactones is described. (-)-(R)-Phoracantholide I ((-)-1; Scheme 2) was synthesized by asymmetric and chemoselective reduction of the side-chain C=O group of (-)-4-(1-nitro-2-oxocyclohexyl)butan-2-one ((-)-6

Full text of DOI:10.1002/hlca.19900730226

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