129648-69-7Relevant academic research and scientific papers
Transition-state stabilization and molecular recognition: Acceleration of phosphoryl-transfer reactions by an artificial receptor
Tecilla, Paolo,Chang, Suk-Kyu,Hamilton, Andrew D.
, p. 9586 - 9590 (2007/10/02)
An artificial receptor that is complementary to the proposed trigonal-bipyramidal intermediate for phosphoryl-transfer reactions has been designed. Kinetic measurements with 31P NMR methods show that the receptor causes up to a 10-fold acceleration in the aminolysis of phosphorodiamidic chloride derivatives, proceeding via an associative mechanism.
