129660-76-0Relevant articles and documents
BAKER'S YEAST CATALYZED ASYMMETRIC CYCLOADDITION OF NITRILEOXIDES TO C=C BOND : IMPROVED CHIRAL RECOGNITION BY USING β-CYCLODEXTRIN
Rao, K. Rama,Bhanumathi, N.,Sattur, P. B.
, p. 3201 - 3204 (1990)
Baker's yeast catalyzes for the first time the asymmetric cycloaddition reaction of arylsubstituted nitrileoxides 1 to vinylpyridines 2 to yield optically active 2-isoxazolines 3.The stereoselectivity is enhanced by fixing the geometry of both dipole and dipolarophile by using β-cyclodextrin as an additional binding cavity along with Baker's yeast.