1296786-52-1Relevant academic research and scientific papers
Remote functionalisation via sodium alkylamidozincate intermediates: Access to unusual fluorenone and pyridyl ketone reactivity patterns
Crawford, James J.,Fleming, Ben J.,Kennedy, Alan R.,Klett, Jan,O'Hara, Charles T.,Orr, Samantha A.
, p. 3772 - 3774 (2011)
Treating fluorenone or 2-benzoylpyridine with the sodium zincate [(TMEDA)·Na(μ-tBu)(μ-TMP)Zn(tBu)] in hexane solution, gives efficient tBu addition across the respective organic substrate in a highly unusual 1,6-fashion, p
