129705-30-2

Usage

General Description

"(3S,6S)-2,7-DIMETHYL-3,6-OCTANEDIOL" is a chemical compound with the molecular formula C10H22O2. It is an organic compound that belongs to the family of alcohols. (3S,6S)-2,7-DIMETHYL-3,6-OCTANEDIOL is classified as a diol, meaning it contains two hydroxyl groups. It has a specific stereochemistry, with a configuration of (3S,6S), which refers to the arrangement of the substituent groups around the chiral centers. (3S,6S)-2,7-DIMETHYL-3,6-OCTANEDIOL is often used as a building block in the synthesis of complex organic molecules, and its hydroxyl groups make it a versatile intermediate for the preparation of various derivatives with different properties and applications.

InChI:InChI=1/C10H22O2/c1-7(2)9(11)5-6-10(12)8(3)4/h7-12H,5-6H2,1-4H3/t9-,10-/m0/s1

Upstream product

• 16736-42-8 2,7-dimethyl-octa-2,6-diene 
• 51513-41-8 2,7-dimethyl-octane-3,6-dione 
• 79516-59-9 (3S)-3-hydroxypentanoic acid 
• 30414-53-0 methyl propanoyl acetate 
• 42558-50-9 methyl (S)-3-hydroxyvalerate 

Downstream Products

• 137151-97-4 (2R,5R)-2,5-diisopropyl-1-phenylphospholane 
• 1032191-67-5 (+)-3,3',4,4'-tetramethyl-5,5'-diphenyl-1,1'-(2,7-dimethyloctane-3,6-dioxy)-2,2'-biphosphole 
• 136705-65-2 (-)-1,2-bis[(2R,5R)-2,5-diisoprohylphospholano]benzene 
• 136705-63-0 1,2-bis((2R,5R)-2,5-diisopropylphospholano)ethane 

Relevant academic research and scientific papers

Synthesis of (±)-trans-2,5-diisopropylborolane

The cyclic hydroboration of 2,7-dimethyl-2,6-octadiene (6) was studied. It was found that the stereochemical outcome of the reaction was dependent upon the solvent, temperature, time and the nature of the borane reagent. Pure racemic trans-2,5-diisopropyl

New chiral phospholanes; synthesis, characterization, and use in asymmetric hydrogenation reactions

We describe the practical synthesis of enantiomerically pure trans-2,5-disubstituted-1-phenylphospholanes which are then employed in the preparation of a new series of C2-symmetric bis- and C3-symmetric tris(phospholane) ligands. A versatile three-step route to the important chiral 1,4-diol intermediates, used in the phosphine syntheses, is outlined. Rhodium complexes bearing the new phosphine ligands were prepared and shown to act as efficient catalyst precursors for the enantioselective hydrogenation of various unsaturated substrates.

Remote Stereocontrol by utilizing Intramolecular Carbonyl Reduction with Boranes

A simple and efficient method for the remote (1,4- and/or 1,5-) stereocontrol was realized by utilizing an intramolecular carbonyl reduction with ThexBH2 (Thex = 1,1,2-trimethylpropyl).