51513-41-8Relevant articles and documents
Diacylation of activated olefins promoted by electrochemically generated NO3·
Shono,Soejima,Takigawa,Yamaguchi,Maekawa,Kashimura
, p. 4161 - 4164 (1994)
It has been found in this study that an acyl radical is formed by the reaction of an aldehyde with a radical NO3· generated by the anodic oxidation of NO3- and the reaction of this acyl radical with activated olefins lead to the formation of a diacylated compound.
3′,3′-N-bis-desmethyl-3′-N-cycloalkyl erythromycin derivatives as LHRH antagonists
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, (2008/06/13)
Disclosed are 3′,3′-N-bis-desmethyl-3′-N-cycloalkyl-6-O-methyl-11-deoxy-11,12-cyclic carbamate erythromycin A derivatives which are antagonists of lutenizing hormone-releasing hormone (LHRH). Also disclosed are pharmaceutical compositions comprising the compounds, to methods of using the compounds and to the process of making the same.
Preparation et oxydation anodique d'acides β-cetaliques. Application a la synthese de γ-bisdioxolannes symetriques et des γ-dicetones derivees.
Einhorn, Jacques,Soulier, Jean-Louis,Bacquet Cathy,Lelandais Daniel
, p. 584 - 587 (2007/10/02)
Anoxic oxidation of carboxylic acids with β-dioxolane substituents leads to good yields of symmetrical γ-bisdioxolanes.Hydrolysis of these compounds easily provides the corresponding γ-diketones.The synthesis of the starting acids is described.