129725-99-1

Basic information

• Product Name: Ni(S₂COC₆H₁₁)2(PCH₃(C₆H₅)2)
• CAS NO: 129725-99-1
• Molecular Weight: 609.501
• Mol File: 129725-99-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Ni(S₂COC₆H₁₁)2(PCH₃(C₆H₅)2)(CAS DataBase Reference)
• NIST Chemistry Reference: Ni(S₂COC₆H₁₁)2(PCH₃(C₆H₅)2)(129725-99-1)
• EPA Substance Registry System: Ni(S₂COC₆H₁₁)2(PCH₃(C₆H₅)2)(129725-99-1)

Safety Data

• Hazardous Substances Data: 129725-99-1(Hazardous Substances Data)

Upstream product

• 53566-81-7 bis(cyclohexylxanthato)nickel(II) 
• 1486-28-8 diphenyl(methyl)phosphine 

Downstream Products

• 53566-81-7 bis(cyclohexylxanthato)nickel(II) 

Relevant articles and documents

Reactions between Bis(O-alkyl dithiocarbonato)nickel(II) Complexes and Phosphines. Formation of a Dithiocarbonate Complex of Nickel(II):

The behaviour of O-alkyl dithiocarbonato complexes, , towards several phosphines has been studied.Depending on the S2COR derivative and phosphine (L) used, octahedral complexes , paramagnetic five-co-ordinate complexes , and square-planar (R=Et or cyclo-C6H11) and complexes have been obtained.The reaction of (R=Me, Et, or cyclo-C6H11) with an excess of dppe gives which is the first NiII-dithiocarbonate complex described.This compound reacts with MeI and C3H5Br to give (X=I or Br).There is no reaction with Lewis-base N donors or with carbon monoxide.