Reactions between Bis(O-alkyl dithiocarbonato)nickel(II) Complexes and Phosphines. Formation of a Dithiocarbonate Complex of Nickel(II):

DOI: 10.1039/DT9870000281

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 281 - 284 (1987)

Update date:2022-08-05

Topics:

Authors:

Perpinan, Maria F.

Ballester, Loreto

Gonzalez-Casso, Maria E.

Santos, Amelia

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/DT9870000281

The behaviour of O-alkyl dithiocarbonato complexes, , towards several phosphines has been studied.Depending on the S2COR derivative and phosphine (L) used, octahedral complexes , paramagnetic five-co-ordinate complexes , and square-planar (R=Et or cyclo-C6H11) and complexes have been obtained.The reaction of (R=Me, Et, or cyclo-C6H11) with an excess of dppe gives which is the first Ni^II-dithiocarbonate complex described.This compound reacts with MeI and C3H5Br to give (X=I or Br).There is no reaction with Lewis-base N donors or with carbon monoxide.

Full text of DOI:10.1039/DT9870000281

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:Ni(S₂COC₆H₁₁)2(PCH₃(C₆H₅)2)

Cas No:129725-99-1

R&D Labs maybe for 129725-99-1

ShenZhen InnoSyn Biotech Co.,Ltd

website:http://www.innosyns.com

Contact:+86-755-28351685

Address:Floor 5 & 6, Building A1, HAIKEXING Strategic Innovative Industrial Park, 16 BaoShan Road, PingShan District
WUHAN WELLSONG INT'L CO.,LTD

Contact:+86-27-85733560

Address:NO.308,QINGNIAN RD.,WUHAN,CHINA
SJZ Chenghui Chemical Co., Ltd.

Contact:86-311-87713916

Address:no.368 youyi north avenue
Jiaozuo Zhongwen Trading Coporation Limited

Contact:+86 0391-3553810

Address:East Renmin Road
Jiangsu Hualun Chemical Industry Co., Ltd

website:http://www.hualunchem.com

Contact:+86-0514-86464168 86507985

Address:39# Middle Renmin Road, Dinghuo Town

Relevant to this article

Different Active-Site Loop Orientation in Serine Hydrolases versus Acyltransferases

Doi:10.1002/cbic.201000693
(2011)
Synthesis of 2H-indazolo[2,1-b]phthalazine-1,6,11(13H)-trione derivatives using wet cyanuric chloride under solvent-free condition

Doi:10.1002/jccs.201000198
(2010)
Studies directed toward the synthesis of glycopeptide antibiotic teicoplanin: First synthesis of the N-terminal 14-membered ring

Doi:10.1021/jo00046a031
(1992)
Facile synthesis of 3,4-dihalofurans via electrophilic iodocyclization

Doi:10.1039/c1cc10584a
(2011)
A new three-step domino Knoevenagel-hetero-Diels-Alder oxidation reaction

Doi:10.1016/j.tetlet.2011.02.081
(2011)
Design, synthesis, radiolabeling, and in vitro and in vivo evaluation of bridgehead iodinated analogues of N -{2-[4-(2-methoxyphenyl)piperazin-1-yl] ethyl}- N -(pyridin-2-yl)cyclohexanecarboxamide (WAY-100635) as potential SPECT ligands for the 5-HT_1A receptor

Doi:10.1021/jm1009956
(2011)

Article Doi