1297593-95-3Relevant academic research and scientific papers
CaII-Catalyzed Alkenylation of Alcohols with Vinylboronic Acids
Leb?uf, David,Presset, Marc,Michelet, Bastien,Bour, Christophe,Bezzenine-Lafollée, Sophie,Gandon, Vincent
, p. 11001 - 11005 (2015)
Direct alkenylation of a variety of alcohols with vinylboronic acids has been accomplished using the air-stable calcium(II) complex Ca(NTf2)2 under mild conditions with short reaction times. For reluctant transformations, an ammonium salt was used as an additive to circumvent the reactivity issue. Cross-coupling: Direct alkenylation of a variety of alcohols with vinylboronic acids has been accomplished using the air-stable calcium(II) complex Ca(NTf2)2 under mild conditions with short reaction times (see scheme)
Cu(OTf)2-catalyzed arylmethylation of terminal alkynes with benzylic alcohols under ligand-, base-, and additive-free reaction conditions
Ren, Kai,Li, Pinhua,Wang, Lei,Zhang, Xiuli
supporting information; experimental part, p. 2753 - 2759 (2011/04/27)
An effective, convenient, and mild coupling reaction of benzylic alcohols with terminal alkynes has been developed. As an effective Lewis acid, Cu(OTf)2-catalyzed arylmethylation of terminal alkynes with benzylic alcohols generated the correspo
