129760-86-7Relevant academic research and scientific papers
Synthesis of diols using the hypervalent iodine(III) reagent, phenyliodine(III) bis(trifluoroacetate)
?elik, Murat,Alp, Cemalettin,Co?kun, Betül,Gültekin, M. Serdar,Balci, Metin
, p. 3659 - 3663 (2007/10/03)
1,2- and 1,3-Bis(trifluoroacetoxy) alcohols are easily obtained from the one-pot reaction of alkenes with phenyliodine(III) bis(trifluoroacetate) (PIFA) in the absence of any additive or catalyst. The products were converted into the corresponding diols by ammonolysis. The use of bicyclic alkenes has shown that rearranged 1,3-diacetoxy alcohols are mostly formed as the major products.
Synthesis and characterization of norbornanediol isomers and their fluorinated analogues
Grayson, Scott M.,Long, Brian K.,Kusomoto, Shiro,Osborn, Brian P.,Callahan, Ryan P.,Chambers, Charles R.,Willson, C. Grant
, p. 341 - 344 (2007/10/03)
Fluorinated norbornene monomers exhibit the requisite properties for inclusion in 157 nm photoresists, but traditional addition and radical polymerizations with these monomers have failed. Norbornanediols provide an alternate route to these materials via condensation polymerization, and methods have been developed for the efficient synthesis of the exo-2-syn-T- and endo-2-exo-3-dihydroxynorbornanes. Synthesis of the fluorinated analogues is complicated by steric and electronic effects; however, a high-yielding synthesis of endo-2-exo-3-dihydroxynorbornane bearing a 5-endo-[2,2-bis(trifluoromethyl) hydroxyethyl] substituent is reported.
RUTHENIUM-CATALYZED OXIDATION OF 2,3-EPOXYNORBORNANE. INFLUENCE OF THE NATURE OF THE REOXIDIZING REAGENT.
Tenaglia, A.,Terranova, E.,Waegell, B.
, p. 1157 - 1158 (2007/10/02)
The nature of the reoxidizing reagent plays a decisive role in the outcome of the ruthenium-catalyzed oxidation of 2,3-epoxynorbornane.
