1298024-05-1Relevant academic research and scientific papers
Total synthesis of (-)-sessilifoliamide C and (-)-8-epi-stemoamide
Hoye, Adam T.,Wipf, Peter
, p. 2634 - 2637 (2011)
A convergent route featuring [3,3]-sigmatropic rearrangements of a linchpin azepinopyrrolidine served to install two of the four contiguous stereocenters present in the tricyclic Stemona alkaloids sessilifoliamide and stemoamide. In addition to the first total synthesis of (-)-sessilifoliamide C, a potential biosynthetic relationship between the sessilifoliamides and previously reported Stemona alkaloids is presented.
