129844-44-6Relevant academic research and scientific papers
Anti-Selective Reaction of α-Sulfenyl Acetals with Silylated Carbon Nucleophiles. Scope, Limitation, and Mechanism
Kudo, Kazuaki,Hashimoto, Yukihiko,Sukegawa, Makoto,Hasegawa, Masaki,Saigo, Kazuhiko
, p. 579 - 587 (2007/10/02)
In the presence of a Lewis acid, α-sulfenyl acetals 1 reacted with various silylated carbon nucleophiles 2 to give anti adducts (anti-3) with high diastereoselectivity.The stereochemistry was only slightly affected by the reaction conditions, such as temp
Anti-Cram Selective Reaction of α-Sulfenyl Acetals with Silylated Carbon Nucleophiles
Saigo, Kazuhiko,Kudo, Kazuaki,Hashimoto, Yukihiko,Kimoto, Hiroki,Hasegawa, Masaki
, p. 941 - 944 (2007/10/02)
α-Sulfenyl acetals reacted smoothly with silylated carbon nucleophiles such as silyl enol ether, ketene silyl acetal, and allylsilane in the presence of a catalytic amount of Lewis acid mainly to give anti-Cram adducts with high diastereoselectivity by th
