129844-61-7Relevant academic research and scientific papers
Anti-Cram Selective Reaction of α-Sulfenyl Acetals with Silylated Carbon Nucleophiles
Saigo, Kazuhiko,Kudo, Kazuaki,Hashimoto, Yukihiko,Kimoto, Hiroki,Hasegawa, Masaki
, p. 941 - 944 (2007/10/02)
α-Sulfenyl acetals reacted smoothly with silylated carbon nucleophiles such as silyl enol ether, ketene silyl acetal, and allylsilane in the presence of a catalytic amount of Lewis acid mainly to give anti-Cram adducts with high diastereoselectivity by th
