1300038-72-5

Basic information

• Product Name: 2-(2-bromo-5-nitrobenzyl)-2-nitrocycloheptanone
• CAS NO: 1300038-72-5
• Molecular Weight: 371.188
• Mol File: 1300038-72-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-(2-bromo-5-nitrobenzyl)-2-nitrocycloheptanone(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(2-bromo-5-nitrobenzyl)-2-nitrocycloheptanone(1300038-72-5)
• EPA Substance Registry System: 2-(2-bromo-5-nitrobenzyl)-2-nitrocycloheptanone(1300038-72-5)

Safety Data

• Hazardous Substances Data: 1300038-72-5(Hazardous Substances Data)

Upstream product

• 939-82-2 1-bromo-2-(bromomethyl)-4-nitrobenzene 
• 13154-27-3 2-nitrocycloheptanone 
• 99-08-1 1-methyl-3-nitrobenzene 

Relevant articles and documents

Synthesis of benzo- and naphtho-fused bicyclo[n.3.1]alkane frameworks with a bridgehead nitrogen function by palladium-catalyzed intramolecular α′-arylation of α-nitroketones

The C-alkylation of cyclic α-nitroketones with α-halobenzyl halides in the presence of DBU followed by a Pd-catalyzed intramolecular C-arylation afforded benzo-and naphtho-fused bicyclo[n.3.1]alkane derivatives (n = 3, 4, 5) in excellent overall yields for the two-step sequence. In some of the reactions starting from α-nitrocyclooctanone, the major products were fused indane derivatives arising from an intramolecular attack of an intermediate Pd species onto the carbonyl group, followed by elimination.