1300118-05-1Relevant articles and documents
Catalytic palladium phosphination: Modular synthesis of C 1-symmetric biaryl-based diphosphines
Bonnafoux, Laurence,Gramage-Doria, Rafael,Colobert, Francoise,Leroux, Frederic R.
, p. 11008 - 11016 (2011/10/19)
A new family of C1-symmetric bis(diphenylphosphino)biphenyls have been prepared starting from readily available ortho,ortho′- dihalobiphenyl precursors by a palladium-catalyzed C-P coupling reaction. This process does not require the use of an
Through-space J(P,P) and J(P,F) spin-spin coupling in C1- symmetric biaryl diphosphanes
Bonnafoux, Laurence,Ernst, Ludger,Leroux, Frederic R.,Colobert, Francoise
experimental part, p. 3387 - 3397 (2011/09/20)
The first simultaneous 31P,31P and 31P,19F solution-phase through-space nuclear spin-spin coupling in biphenyl derivatives is reported. The magnitudes of the coupling constants are in the range 5.3-28.7 and 2.3-