13003-31-1Relevant academic research and scientific papers
Synthetic uses of thioesters of trifluoromethylated acids. Part 2: Reactions with alkenes
Billard, Thierry,Roques, Nicolas,Langlois, Bernard R.
, p. 3069 - 3072 (2007/10/03)
The photolysis of trifluoromethanethiosulfonates (CF3SO2SR) or trifluorothioacetates (CF3COSR) in the presence of alkenes provides (trifluoromethyl)alkanes or β-sulfanyl (trifluoromethyl)alkanes. The formation of these compounds can be controlled by the nature and the ratio of the reactants. (C) 2000 Published by Elsevier Science Ltd.
Synthetic Uses of Thio- and Selenoesters of Trifluoromethylated Acids. 1. Preparation of Trifluoromethyl Sulfides and Selenides
Billard, Thierry,Roques, Nicolas,Langlois, Bernard R.
, p. 3813 - 3820 (2007/10/03)
Trifluorothioacetates (CF3CO-S-R, from (CF3CO)2O and thiols) as well as trifluoromethanethio-or trifluoromethaneselenosulfonates (CF3SO2-Y-R; Y = S, Se; from CF3SO2Na, RYYR, and Br2) can be formally decarbonylated or desulfonylated, respectively, provided that they are photolyzed at 40°C in the presence of 1 equiv of the corresponding disulfide or diselenide. Trifluoromethyl sulfides or selenides are obtained, and the added disulfide (or diselenide) is recovered after reaction. In such a way, S-(trifluoromethyl)cysteine derivatives can be obtained.
