130052-47-0Relevant academic research and scientific papers
Regio- and stereoselective incorporation of a13C nuclide into D-ribo-phytosphingosine via SmI2-mediated C-C formation with13C-labeled isocyanide
Murakami, Masahiro,Ito, Hajime,Ito, Yoshihiko
, p. 185 - 186 (2007/10/03)
Preparation of a 13C-labeled isocyanide and its application to the total synthesis of [2-13C]D-ribo-C18-phytosphingosine are described. The synthesis of the labeled phytosphingosine is based on the use of the isocyanide as a 13CH-NH2 precursor in the SmI2-mediated three-component coupling reaction, wherein regio- and stereoselective incorporation of a 13C nuclide in the carbon skeleton is achieved.
Synthesis of the Stereoisomers of 1-O-(2'-Methoxyhexadecyl)glycerol and some Phosphocholine Derivatives
Staellberg, Gunnel A.M.
, p. 368 - 376 (2007/10/02)
All four stereoisomers of 1-O-(2'-methoxyhexadecyl)glycerol have been synthesized.The stereoisomer obtained from biological material was shown to have the 2'R, 2S configuration.The corresponding phospholipid (2'R)-1-O-(2'-methoxyhexadecyl)-sn-glycero-3-ph
