175696-46-5

Upstream product

• 175696-42-1 ((R)-1-Benzyloxymethyl-pentadecyloxy)-triisopropyl-silane 
• 175696-43-2 (R)-2-(triisopropylsiloxy)hexadecanal 
• 80522-42-5 triisopropylsilyl trifluoromethanesulfonate 
• 130052-47-0 (R)-1-benzyloxy-2-hydroxyhexadecane 

Downstream Products

• 175696-47-6 C₃₈⁽¹³⁾CH₇₃NO₅Si 

Relevant academic research and scientific papers

Regio- and stereoselective incorporation of a13C nuclide into D-ribo-phytosphingosine via SmI2-mediated C-C formation with13C-labeled isocyanide

Preparation of a 13C-labeled isocyanide and its application to the total synthesis of [2-13C]D-ribo-C18-phytosphingosine are described. The synthesis of the labeled phytosphingosine is based on the use of the isocyanide as a 13CH-NH2 precursor in the SmI2-mediated three-component coupling reaction, wherein regio- and stereoselective incorporation of a 13C nuclide in the carbon skeleton is achieved.