13013-86-0Relevant academic research and scientific papers
CARBOXYLIC DITHIOCARBAMIC ACID ANHYDRIDE COMPOUNDS AND COMPOSITIONS THEREOF
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Paragraph 228, (2021/07/24)
The present invention relates to certain carboxylic dithiocarbamic acid anhydride compounds compounds and their use as photoinitiators in living free-radical polymerization reactions. The invention also relates to curable or cross-linkable compositions comprising the carboxylic dithiocarbamic acid anhydride compounds of the invention.
Copper-Catalyzed Coupling of Acyl Chlorides with gem-Difluorinated Organozinc Reagents via Acyl Dithiocarbamates
Ashirbaev, Salavat S.,Levin, Vitalij V.,Struchkova, Marina I.,Dilman, Alexander D.
, p. 478 - 483 (2017/12/15)
A cross-coupling of acyl chlorides with gem-difluorinated organozinc reagents affording difluorinated ketones is described. In the reaction, acyl chlorides are first treated with potassium dithiocarbamate to generate S-acyl dithiocarbamates, which couple with organozincs in the presence of a copper(I) catalyst.
