130131-79-2Relevant articles and documents
Cyclo-palladated aryloxazolines: preparation and carbonylation reactions. Molecular and crystal structure of di-μ-acetato-bisdipalladium(II)
Balavoine, G.,Clinet, J. C.,Zerbib, P.,Boubekeur, K.
, p. 259 - 275 (2007/10/02)
Aryloxazolines, with various substituents on the aromatic ring, have given dimeric cyclo-palladated complexes by reaction with palladium acetate.Steric interaction between ligands causes opening of the molecular structure, as reflected in a long Pd...Pd distance.This structural feature and the fluxionality in solution may be responsible for an unexpected carbonylation reaction which gave diarylketones in good yields.