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53416-46-9

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53416-46-9 Usage

General Description

2-(4-Methoxyphenyl)-4,4-dimethyl-4,5-dihydro-1,3-oxazole, also known as DMO, is a chemical compound with a molecular formula C12H15NO2. It is a member of the oxazole family and contains a methoxyphenyl group attached to a dimethyl oxazole ring. DMO is commonly used as an intermediate in the synthesis of pharmaceuticals and agrochemicals. It has also been studied for its potential antifungal and antibacterial properties. Additionally, DMO has been used in the development of organic light-emitting diodes (OLEDs) and can act as a fluorescence emitter in organic electroluminescent devices. Overall, DMO is a versatile chemical compound with important applications in various industries including pharmaceuticals, agriculture, and electronics.

Check Digit Verification of cas no

The CAS Registry Mumber 53416-46-9 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 5,3,4,1 and 6 respectively; the second part has 2 digits, 4 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 53416-46:
(7*5)+(6*3)+(5*4)+(4*1)+(3*6)+(2*4)+(1*6)=109
109 % 10 = 9
So 53416-46-9 is a valid CAS Registry Number.
InChI:InChI=1/C12H15NO2/c1-12(2)8-15-11(13-12)9-4-6-10(14-3)7-5-9/h4-7H,8H2,1-3H3

53416-46-9SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 18, 2017

Revision Date: Aug 18, 2017

1.Identification

1.1 GHS Product identifier

Product name 2-(4-methoxyphenyl)-4,4-dimethyl-5H-1,3-oxazole

1.2 Other means of identification

Product number -
Other names 4,5-dihydro-4,4-dimethyl-2-(4-methoxyphenyl)oxazole

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:53416-46-9 SDS

53416-46-9Relevant articles and documents

Preparation of Polyfunctionalized Aromatic Nitriles from Aryl Oxazolines

Hess,Guelen,Alandini,Mourati,Guersoy,Knochel

, (2021/12/06)

A selective ortho,ortho’-functionalization of readily available aryl oxazolines by two successive magnesiations with sBu2Mg in toluene followed by trapping reactions with electrophiles, such as (hetero)aryl iodides or bromides, iodine, tosyl cyanide, ethyl cyanoformate or allylic bromides (39 examples, 62–99 % yield) is reported. Treatment of these aryl oxazolines with excess oxalyl chloride and catalytic amounts of DMF (50 °C, 4 h) provided the corresponding nitriles (36 examples, 73–99 % yield). Conversions of these nitriles to valuable heterocycles are reported, and a tentative mechanism is proposed.

Substitution Effect on 2-(Oxazolinyl)-phenols and 1,2,5-Chalcogenadiazole -Annulated Derivatives: Emission-Color-Tunable, Minimalistic Excited-State Intramolecular Proton Transfer (ESIPT)-Based Luminophores

G?bel, Dominik,Rusch, Pascal,Duvinage, Daniel,Stauch, Tim,Bigall, Nadja-C.,Nachtsheim, Boris J.

supporting information, p. 14333 - 14355 (2021/10/20)

Minimalistic 2-(oxazolinyl)-phenols substituted with different electron-donating and -withdrawing groups as well as 1,2,5-chalcogenadiazole-annulated derivatives thereof were synthesized and investigated in regard to their emission behavior in solution as well as in the solid state. Depending on the nature of the incorporated substituent and its position, emission efficiencies were increased or diminished, resulting in AIE or ACQ characteristics. Single-crystal analysis revealed J- and H-type packing motifs and a so-far undescribed isolation of ESIPT-based fluorophores in the keto form.

Aerobic C(sp2)-H Hydroxylations of 2-Aryloxazolines: Fast Access to Excited-State Intramolecular Proton Transfer (ESIPT)-Based Luminophores

G?bel, Dominik,Clamor, Nils,Lork, Enno,Nachtsheim, Boris J.

supporting information, p. 5373 - 5377 (2019/06/07)

The direct hydroxylation of 2-aryloxazolines via a deprotonative magnesiation using TMPMgCl·LiCl and subsequent oxidation with molecular oxygen or air as a green oxidant is reported. This method proceeds under mild conditions at room temperature with high regioselectivity and chemoselectivity. The obtained phenols exhibit tunable luminescence properties, induced by excited-state intramolecular proton transfer. This method opens a new opportunity for the sustainable synthesis of luminescent organic molecules.

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