130156-57-9Relevant academic research and scientific papers
New Fluorine-containing Building Blocks from Trifluoroethanol. 1.
Patel, Sunita T.,Percy, Jonathan M.,Wilkes, Robin D.
, p. 9201 - 9216 (1995)
A new fluorine containing acyl anion equivalent 1,1-difluoro-2-lithio-2-ethene 12 has been prepared from trifluoroethanol and trapped with a number of electrophiles in good yield.Effective electrophiles included Group(IV) halides a
A STABILISED DIFLUOROVINYL ANION
Percy, Jonathan M.
, p. 3931 - 3932 (1990)
a new difluorovinyl anion is described which can be generated in situ and quenched with electrophiles in good yields.Chelation is believed to be responsible for stabilisation of this anion, a simple alkoxy substituted analogue showing markedly different b
