1301717-33-8

Basic information

• Product Name: (S)-1-methoxy-4-(2-phenylbut-3-en-2-yl)benzene
• Synonyms: (S)-1-methoxy-4-(2-phenylbut-3-en-2-yl)benzene
• CAS NO: 1301717-33-8
• Molecular Weight: 238.329
• Mol File: 1301717-33-8.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (S)-1-methoxy-4-(2-phenylbut-3-en-2-yl)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-1-methoxy-4-(2-phenylbut-3-en-2-yl)benzene(1301717-33-8)
• EPA Substance Registry System: (S)-1-methoxy-4-(2-phenylbut-3-en-2-yl)benzene(1301717-33-8)

Safety Data

• Hazardous Substances Data: 1301717-33-8(Hazardous Substances Data)

Upstream product

• 69519-11-5 2-(4-methoxyphenyl)-[1,3,2]-dioxaborolane 
• 768392-43-4 (E)-diethyl (3-phenylbut-2-en-1-yl) phosphate 
• 155826-85-0 4-methoxylphenylboronic acid 1,3-propanediol ester 
• 157397-76-7 (E)-methyl 3-phenylbut-2-enyl carbonate 
• 213596-33-9 2-(4-methoxyphenyl)-5,5-dimethyl-1,3,2-dioxaborolane 
• 124604-57-5 [(1E)-3-chloro-1-methylprop-1-en-1-yl]benzene 
• 1579250-14-8 (E)-3-phenyl-2-butenyl picolinate 
• 54976-38-4 (E)-3-phenylbut-2-en-1-ol 
• 54976-37-3 (Z)-3-phenyl-2-buten-1-ol 
• 1257661-14-5 (p-MeOC₆H₄)(Ph)(CH₃)CB(pinacol) 
• 1112-56-7 tetravinyltin (IV) 
• 171364-79-7 2-(4-methoxyphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 

Downstream Products

• 1301717-29-2 (S)-2-(4-methoxyphenyl)-2-phenylpropan-1-ol 
• 1334512-30-9 (S)-3-(4-methoxyphenyl)-3-phenyl-1-butanol 

Relevant articles and documents

Synthesis of quaternary carbon stereocenters by copper-catalyzed asymmetric allylic substitution of allyl phosphates with arylboronates

A copper-catalyzed asymmetric allylic substitution of γ,γ- disubstituted allyl phosphates with arylboronates has been developed for the construction of quaternary stereocenters. High regio- and enantioselectivities have been achieved by employing a hydroxy-bearing chiral N-heterocyclic carbene ligand, and both E and Z substrates provide the same enantiomer as the major product. The mechanistic aspect of this catalysis has also been investigated to find that a 1:1 copper/ligand complex is most likely responsible for the present asymmetric catalysis, and the reaction proceeds with almost perfect 1,3-anti stereochemistry with respect to the allylic electrophile.

Enantioselective construction of quaternary stereogenic centers from tertiary boronic esters: Methodology and applications

Pin it down: A range of substrates that bear versatile functional groups with quaternary stereogenic centers have been prepared with very high enantioselectivity from tertiary boronic esters (see scheme; Cb=N,N-diisopropylcarbamoyl, pin=pinacolato). The preparation of allylboronic esters bearing contiguous quaternary and tertiary stereogenic centers, and applications to natural product synthesis are also reported.