768392-43-4

Upstream product

• 98-86-2 acetophenone 
• 945-93-7 ethyl (E)-3-phenylbut-2-enoate 
• 54976-38-4 (E)-3-phenylbut-2-en-1-ol 
• 814-49-3 diethyl chlorophosphate 

Downstream Products

• 768392-48-9 (R)-(-)-3-methyl-3-phenyl-1-pentene 
• 935753-18-7 (R,E)-(3-methylundeca-1,4-dien-3-yl)benzene 
• 1251861-86-5 (R,E)-1-methyl-2-(3-methyl-3-phenylpenta-1,4-dien-1-yl)benzene 
• 1251861-87-6 (R,E)-1-methoxy-4-(3-methyl-3-phenylpenta-1,4-dien-1-yl)benzene 
• 1301717-33-8 (S)-1-methoxy-4-(2-phenylbut-3-en-2-yl)benzene 
• 1334512-29-6 (S)-3-(2-naphthyl)-3-phenyl-1-butene 

Relevant academic research and scientific papers

Synthesis of α-Quaternary Formimides and Aldehydes through Umpolung Asymmetric Copper Catalysis with Isocyanides

A highly regio- and enantioselective copper-catalyzed three-component coupling of isocyanides, hydrosilanes, and γ,γ-disubstituted allylic phosphates/chlorides to afford chiral α-quaternary formimides was enabled by the combined use of our original chiral

Copper-catalyzed asymmetric allylic substitution of allyl phosphates with aryl- and alkenylboronates

The asymmetric allylic substitution of allyl phosphates with aryl- and alkenylboronates catalyzed by a copper/N-heterocyclic carbene complex was developed and the substitution products were obtained with high enantioselectivity (see scheme). To account for the observed influence of the reaction parameters a possible catalytic cycle for this process was proposed. Copyright