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130225-27-3

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130225-27-3 Usage

Uses

Starting material for the synthesis of a variety of ferrocene-based catalysts.

Check Digit Verification of cas no

The CAS Registry Mumber 130225-27-3 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,3,0,2,2 and 5 respectively; the second part has 2 digits, 2 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 130225-27:
(8*1)+(7*3)+(6*0)+(5*2)+(4*2)+(3*5)+(2*2)+(1*7)=73
73 % 10 = 3
So 130225-27-3 is a valid CAS Registry Number.
InChI:InChI=1/C12H11OS.C5H5.Fe/c1-10-6-8-12(9-7-10)14(13)11-4-2-3-5-11;1-2-4-5-3-1;/h2-9H,1H3;1-5H;/t14-;;/m0../s1/rC17H16FeOS/c1-13-9-11-15(12-10-13)20(19)17-8-4-7-16(17)18-14-5-2-3-6-14/h2-12,14,16H,1H3/t16?,20-/m1/s1

130225-27-3 Well-known Company Product Price

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  • TCI America

  • (T2545)  (R)-(p-Toluenesulfinyl)ferrocene  >98.0%(HPLC)(T)

  • 130225-27-3

  • 1g

  • 2,250.00CNY

  • Detail
  • TCI America

  • (T2545)  (R)-(p-Toluenesulfinyl)ferrocene  >98.0%(HPLC)(T)

  • 130225-27-3

  • 5g

  • 6,750.00CNY

  • Detail

130225-27-3SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 10, 2017

Revision Date: Aug 10, 2017

1.Identification

1.1 GHS Product identifier

Product name cyclopenta-1,3-diene,1-[(S)-cyclopenta-1,3-dien-1-ylsulfinyl]-4-methylbenzene,iron(2+)

1.2 Other means of identification

Product number -
Other names (R)-Ferrocenyl p-Tolyl Sulfoxide

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:130225-27-3 SDS

130225-27-3Relevant articles and documents

Two approaches in the synthesis of planar chiral azinylferrocenes

Utepova, Irina A.,Chupakhin, Oleg N.,Serebrennikova, Polina O.,Musikhina, Alexandra A.,Charushin, Valery N.

, p. 8659 - 8667 (2014)

Two synthetic routes to the chiral azinylferrocenes (CAFs) 5 and 15, key intermediates for the synthesis of new enantiomerically enriched P,N-ligands, have been compared. The first approach is based on the palladium-catalyzed cross-coupling reaction of halogenated azines with organozinc derivatives of ferrocenes (the Negishi reaction). The second approach exploits a new synthetic methodology, which provides a shorter pathway, through the direct C-H functionalization of aromatics by the C-C coupling of halogen-free (hetero)arenes with lithium ferrocenes bearing stereogenic C and S atoms. The palladium complexes of P,N-ligands have been used as catalysts for the Tsuji-Trost reaction, which proceeds with high enantioselectivity to give allylic substitution products in good yields.

Intramolecularly sulfur-stabilized silicon cations as Lewis acid catalysts

Rohde, Volker H. G.,Pommerening, Phillip,Klare, Hendrik F. T.,Oestreich, Martin

, p. 3618 - 3628 (2014/08/05)

The synthesis and spectroscopic characterization of previously unprecedented sulfur-stabilized silicon cations are reported. Several 1,3-dithiolan-2-yl- and 1,3-dithian-2-yl-substituted silanes were prepared and successfully transformed into the corresponding silicon cations by hydride abstraction. The silicon-sulfur interaction creates three consecutive stereocenters at three different elements. It is remarkable that the present stereocenter at the silicon atom determines the stereochemical outcome at the formerly prochiral sulfur and carbon atoms with excellent diastereoselectivity. All sulfur-stabilized silicon cations are shown to be potent catalysts in a challenging Diels-Alder reaction. Moreover, structurally related oxazoline-stabilized silicon cations were generated and characterized but found to be unreactive.

Synthesis and reactivity of achiral and of a novel planar chiral thioferrocenoylsilanes

Bonini, Bianca F.,Comes-Franchini, Mauro,Fochi, Mariafrancesca,Mazzanti, Germana,Ricci, Alfredo,Tomasulo, Massimiliano,Varchi, Greta

, p. 407 - 417 (2007/10/03)

The reactions of thioferrocenoylsilanes with organolithium reagents, dienes and reducing agents which afford α-silyl sulphides, dihydrothiopyranes and α-silyl ferrocenyl thiols, respectively, have been investigated. α-Silyl sulphides were further functionalised through carbodesilylation with aldehydes. We also report the synthesis of a new planar chiral thioferrocenoylsilane that gave good diastereomeric excess in the reaction with t-butyllithium, lithium lutidine and 2,3-dimethylbuta-1,3-diene. The 1,1′-bis-thioferrocenoylsilane, too unstable to be isolated, was trapped in situ with dienes.

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