130259-83-5Relevant academic research and scientific papers
Suppression of alkene isomerisation in products from intramolecular Heck reactions by addition of Tl(1) salts
Grigg,Loganathan,Santhakumar,Sridharan,Teasdale
, p. 687 - 690 (2007/10/02)
Palladium catalysed cyclisations creating products possessing spiro-, fused- and bridged-rings, and tetrasubstituted carbon centres as mixtures of double bond isomers are modified to give single products in the presence of Tl(1) salts.
THE SYNTHESIS OF FUSED RING NITROGEN HETEROCYCLES VIA REGIOSPECIFIC INTRAMOLECULAR HECK REACTIONS
Grigg, Ronald,Sridharan, Visuvanathar,Stevenson, Paul,Sukirthalingam, Sukanthini,Worakun, Tanachat
, p. 4003 - 4018 (2007/10/02)
A series of palladium (and in some cases rhodium) catalysed regiospecific 5-exo-, 6-endo- and 6-exo-trig cyclisations of aryl iodides and vinyl bromides onto proximate alkenes or heteroaromatic rings (indole, pyrrole) lead to a wide variety of fused ring
