130274-38-3Relevant academic research and scientific papers
Palladium-Catalyzed Regio- and Stereoselective Synthesis of (E)-1,3-Bissilyl-6-arylfulvenes from Aryl Iodides and Silylacetylenes
Suzuki, Souta,Kinoshita, Hidenori,Miura, Katsukiyo
supporting information, p. 1612 - 1616 (2019/03/08)
An efficient synthetic route to (E)-1,3-bissilyl-6-arylfulvenes has been developed. The reaction of aryl iodides with trimethylsilylacetylene in the presence of a catalytic amount of PdBr2 gives 6-aryl-1,3-bis(trimethylsilyl)fulvenes in good to
A new synthesis of substituted fulvenes
Lee, Gary C. M.,Tobias, Brian,Holmes, Judy M.,Harcourt, Dale A.,Garst, Michael E.
, p. 9330 - 9336 (2007/10/02)
A new fulvene synthesis results from the palladium-catalyzed [2 + 2 + 2] annulation of 1 mol of a β-substituted vinyl iodide and 2 mol of a monosubstituted acetylene. This variant of the Heck reaction tolerates a wide range of substrate substituents with
