130288-45-8Relevant articles and documents
Synthesis of (-)-Probetaenone I: Structural Confirmation of Biosynthetic Precursor of Betaenone B
Miki, Shokyo,Sato, Yoshihiro,Tabuchi, Hiroyasu,Oikawa, Hideaki,Ichihara, Akitami,Sakamura, Sadao
, p. 1228 - 1229 (2007/10/02)
(-)-Probetaenone I (1) has been synthesized by an intramolecular Diels-Alder reaction and, thereby, its structure has been clearly confirmed; in the biosynthesis of betaenone B (2) the stereochemistry of the C-8 hydroxylation of (1) was proved to involve retention of configuration.