13032-12-7

Usage

Uses

Used in Academic Research:
Pyridine, 1,4-dihydro-1-(trimethylsilyl)-4-[1-(trimethylsilyl)-4(1H)-pyridinylidene]is used as a specialized reagent for academic research, particularly in the fields of organic chemistry and materials science. Its unique structure and properties make it a valuable tool for studying chemical reactions and interactions.
Used in Industrial Research:
In industrial research settings, Pyridine, 1,4-dihydro-1-(trimethylsilyl)-4-[1-(trimethylsilyl)-4(1H)-pyridinylidene]is employed as a reagent to aid in the development of new materials and chemical processes. Its increased volatility due to the trimethylsilyl groups can be advantageous for certain analytical techniques and applications.
Used in Analytical Chemistry:
Pyridine, 1,4-dihydro-1-(trimethylsilyl)-4-[1-(trimethylsilyl)-4(1H)-pyridinylidene]is used as a reagent in analytical chemistry to enhance the detection and analysis of compounds. The trimethylsilyl groups contribute to its volatility, which can be beneficial for techniques such as gas chromatography and mass spectrometry.

Upstream product

• 553-26-4 4,4'-bipyridine 
• 75-77-4 chloro-trimethyl-silane 

Downstream Products

• 31935-72-5 p-chloro-N,N-bis(trimethylsilyl)aniline 
• 31945-23-0 N_.N-Bis-trimethylsilyl-p-cyanoanilin 
• 4147-89-1 1,1,1-trimethyl-N-phenyl-N-(trimethylsilyl)-silanamine 
• 53783-47-4 N,O-bis(trimethylsily1)phenylhydroxylamine 
• 1227476-15-4 Azobenzene 
• 31935-68-9 1,1,1-Trimethyl-N-(4-methylphenyl)-N-(trimethylsilyl)silanamine 
• 13735-81-4 1-styrenyloxytrimethylsilane 
• 101765-68-8 Trimethyl-(2-methyl-1-p-tolylsulfanyl-propenyloxy)-silane 

Relevant academic research and scientific papers

Titanium-based molecular squares and rectangles: Syntheses by self-assembly reactions of titanocene fragments and aromatic N-heterocycles

This paper reports on the potential of titanium compounds as building blocks for supramolecular polygons. Self-assembly reactions of low-valent titanocene units and N-heterocyclic bridging ligands lead to novel titanium-based supramolecular squares. Pyraz

Metal-free deoxygenation and reductive disilylation of nitroarenes by organosilicon reducing reagents

A metal-free deoxygenation and reductive disilylation of nitroarenes was achieved using N,N’-bis(trime-thylsilyl)-4,4’-bipyridinylidene (1) under mild and neutral reaction conditions, and a broad functional group tolerance was possible in this reaction. Mono-deoxygenation, giving a synthetically valuable N,O-bis(trimethylsilyl)phe-nylhydroxylamine (7a) as a readily available and safe phenylnitrene source from nitrobenzene, and double-deoxy-genation, giving N,N-bis(trimethylsilyl)anilines 8, were easily controlled by varying the amounts of 1 and reaction temperature as well as adding dibenzothiophene (DBTP). Reaction of 2-arylnitrobenzenes with 1 resulted in the formation of the corresponding carbazoles 14 via in situ-gen-erated phenylnitrene species derived by thermolysis of N,O-bis(trimethylsilyl)phenylhydroxylamines 7, followed by their subsequent intramolecular C H insertion. In addition, the intramolecular N N coupling reaction proceeded in the reduction of 2,2’-dinitrobiphenyl derivatives by 1, giving the corresponding benzo[c]cinnolines.