1303559-75-2Relevant academic research and scientific papers
Gold and bronsted acid catalyzed hydride shift onto allenes: Divergence in product selectivity
Bolte, Benoit,Gagosz, Fabien
supporting information; experimental part, p. 7696 - 7699 (2011/06/27)
A series of allenyl ethers can be transformed into various fused or spiro tetrahydrofurans and tetrahydropyrans following a hydride shift/cyclization sequence. A divergence in product selectivity, which depends on the nature of the catalyst used (Au(I) complex or Bronsted acid), was observed.
