130400-96-3Relevant academic research and scientific papers
Electrophile-induced bromocyclization of γ,δ-unsaturated ketimines to intermediate 1-pyrrolinium salts and their selective conversion into novel 5-alkoxymethyl-2-aryl-3-chloropyrroles and 2-aroylpyrroles
D'Hooghe, Matthias,Buyck, Christophe,Contreras, Jan,De Kimpe, Norbert
scheme or table, p. 3667 - 3669 (2009/02/05)
N-(1-Aryl-2,2-dichloropent-4-enylidene)amines were efficiently transformed into 5-bromomethyl-1-pyrrolinium bromides via electrophile-induced bromocyclization. The latter pyrrolinium salts were converted into novel 5-alkoxymethyl-2-aryl-3-chloropyrroles b
A Convenient Synthesis of 2,2-Dichloro-1-phenyl-1-alkanones and the Corresponding Imines
Kimpe, Norbert De,Coppens, Wim,Welch, John,Corte, Bart De
, p. 675 - 677 (2007/10/02)
N-(2,2-Dichloro-1-phenylalkylidene)isopropylamines were synthesized by deprotonation of N-(2,2-dichloro-1-phenylethylidene)isopropylamine by lithium diisopropylamide and reaction of the resulting 3,3-dichloro-1-azaallylic anion with alkyl bromides or iodi
