130407-76-0

Upstream product

• 40996-91-6 3-vinyl-cyclohex-2-enone 
• 75-16-1 methylmagnesium bromide 
• 62763-42-2 3-methyl-1-vinyl-2-cyclohexenol 

Downstream Products

• 130407-89-5 (3aR,9S,9aR,9bS)-9-Methyl-2-phenyl-9-trimethylsilanyloxy-3a,4,6,7,8,9,9a,9b-octahydro-benzo[e]isoindole-1,3-dione 
• 130407-89-5 (3aR,9R,9aR,9bS)-9-Methyl-2-phenyl-9-trimethylsilanyloxy-3a,4,6,7,8,9,9a,9b-octahydro-benzo[e]isoindole-1,3-dione 
• 130407-88-4 (3aR,9R,9aR,9bS)-9-Methoxy-9-methyl-2-phenyl-3a,4,6,7,8,9,9a,9b-octahydro-benzo[e]isoindole-1,3-dione 
• 130407-88-4 (3aR,9S,9aR,9bS)-9-Methoxy-9-methyl-2-phenyl-3a,4,6,7,8,9,9a,9b-octahydro-benzo[e]isoindole-1,3-dione 
• 130407-83-9 (3aR,9R,9aR,9bS)-9-Hydroxy-9-methyl-2-phenyl-3a,4,6,7,8,9,9a,9b-octahydro-benzo[e]isoindole-1,3-dione 
• 130407-78-2 3-<(trimethylsilyl)oxy>-3-methyl-1-vinylcyclohexene 

Relevant academic research and scientific papers

Conformational biasing in 1,3-oxidative rearrangements of dienols

1-Vinyl-2-cycloalkenols are oxidized to form conjugated dienones in useful yields. Although this oxidative rearrangement is general, severe steric interactions can favor the formation of a conjugated dienal instead of a conjugated dienone. Several heteroc

Effect of allylic substituents on the face selectivity of Diels-Alder reactions of semicyclic dienes

Vinylcyclohexenes substituted allylically on the cyclohexene ring were examined as substrates in the Diels-Alder cycloaddition. In the octalin cycloaddition products, the relative stereochemistry of the one angular hydrogen relative to that of the allylic