130407-76-0Relevant articles and documents
Conformational biasing in 1,3-oxidative rearrangements of dienols
Majetich, George,Nishide, Hisaya,Phillips, Ryan M.,Yu, Jianhua
, p. 225 - 231 (2008/09/17)
1-Vinyl-2-cycloalkenols are oxidized to form conjugated dienones in useful yields. Although this oxidative rearrangement is general, severe steric interactions can favor the formation of a conjugated dienal instead of a conjugated dienone. Several heteroc