13041-77-5Relevant academic research and scientific papers
Rh(III)-Catalyzed Redox-Neutral Annulation of Primary Benzamides with Diazo Compounds: Approach to Isoquinolinones
Wu, Youzhi,Sun, Peng,Zhang, Kaifan,Yang, Tie,Yao, Hequan,Lin, Aijun
, p. 2166 - 2173 (2016)
Reported herein is a Rh-catalyzed redox-neutral annulation of primary benzamides with diazo compounds, representing an efficient and economic protocol to isoquinolinones. The procedure exhibited good functional group tolerability, scalability, and regioselectivity, obviating the need for oxidants, and only environmentally benign N2 and H2O were released. Further utilization of the method provided an alternative route to functionalized isoquinolines.
Formation of Carbon-Carbon Bond on Solid Support: Application of the Stille Reaction
Deshpande, Milind S.
, p. 5613 - 5614 (1994)
Vinyl/Aryl stannanes couple smoothly with polymer bound aryl iodides.The cross-coupled products are obtained in excellent yield and purity after cleavage from the solid support.
Small molecule macroarray construction via palladium-mediated carbon - Carbon bond-forming reactions: Highly efficient synthesis and screening of stilbene arrays
Frei, Reto,Blackwell, Helen E.
supporting information; experimental part, p. 2692 - 2695 (2010/07/02)
(Figure Presented) Arrays of stilbenes have been prepared in high purity by using Heck reactions on planar cellulose support, and demonstrate the compatibility of the small-molecule macroarray platform (see figure) with metal-mediated reactions for the fi
