130412-95-2

Basic information

• Product Name: Benzyl-naphthalen-1-yl-carbodiimide
• Synonyms: Benzyl-naphthalen-1-yl-carbodiimide
• CAS NO: 130412-95-2
• Molecular Weight: 258.323
• Mol File: 130412-95-2.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Benzyl-naphthalen-1-yl-carbodiimide(CAS DataBase Reference)
• NIST Chemistry Reference: Benzyl-naphthalen-1-yl-carbodiimide(130412-95-2)
• EPA Substance Registry System: Benzyl-naphthalen-1-yl-carbodiimide(130412-95-2)

Safety Data

• Hazardous Substances Data: 130412-95-2(Hazardous Substances Data)

Upstream product

• 107544-71-8 1-benzyl-3-(naphthalen-1-yl)thiourea 
• 134-32-7 1-amino-naphthalene 
• 622-78-6 Benzyl isothiocyanate 
• 124316-00-3 1-<<(Triphenylphosphoranylidene)amino>methyl>benzotriazole 
• 86-84-0 1-Naphthyl isocyanate 

Relevant articles and documents

Gram Scalable Method to Synthesize Biscarbodiimides and Asymmetric Monocarbodiimides: A Platform to Access an Array of Phosphaguanidines, Amidines, and Guanidines

A mild, broadly functional group tolerant methodology has been developed to access a variety of mono- and bis-carbodiimides in good yield and high purity on multigram scale. Direct addition into these versatile motifs facilitated the rapid synthesis of a library of novel amidinines, guanidines, and phosphaguandines.

1-(Triphenylphosphorylideneaminomethyl)benzotriazole (BETMIP) a Novel +CH2N= Synthetic Equivalent: Its Application to the Synthesis of Carbodiimides, Imines, Isothiocyanates, Aziridines, and Secondary Amines

One-carbon homologation has been achieved in novel syntheses of the title compounds by one-pot reaction of 1-(triphenylphosphorylideneaminomethyl)benzotriazole (1) with Grignard reagents followed by in situ transformations of the phosphorazene functionality with isocyanates, aldehydes, carbon disulfide, ethylene oxide, and alkyl halides, respectively.