130423-06-2Relevant academic research and scientific papers
REACTIONS OF UNASATURATED COMPOUNDS. CL. REGIOCHEMISTRY AND STEREOCHEMISTRY OF THE ACYLATION OF 2-METHYL-1-BUTEN-3-YNE. THE TRANSFORMATION OF 2H-PYRAN INTO FURAN WITH OXIDATIVE EXTRUSION OF THE CH2 GROUP
Melikyan, G. G.,Babayan, E. V.,Panosyan, G. A.,Palikyan, G. U.,Badanyan, Sh. O.
, p. 830 - 836 (2007/10/02)
The regiochemistry and stereochemistry of the low-temperature acylation of 2-methyl-1-buten-3-yne were investigated.In the case of alkanoyl chlorides 1,4-addition of the acylating agent occurs and is followed by 1,3-chlorotropy in the adducts (1-chloro-2-
