13043-66-8 Usage
Uses
Used in Organic Synthesis:
(Z)-1,1-diethoxytridec-2-ene is used as a reagent in organic synthesis for its ability to participate in various chemical reactions, contributing to the formation of new compounds and materials.
Used in Industrial Applications:
In the industrial sector, (Z)-1,1-diethoxytridec-2-ene is employed as a reagent to facilitate specific chemical processes, enhancing the efficiency and effectiveness of production lines.
Used in Pharmaceutical Industry:
(Z)-1,1-diethoxytridec-2-ene is studied for its potential use in the pharmaceutical industry, leveraging its unique chemical properties for the development of new drugs and medicinal compounds.
Used in Agrochemical Industry:
Similarly, in the agrochemical industry, (Z)-1,1-diethoxytridec-2-ene is being investigated for its possible applications, potentially contributing to the creation of novel agrochemicals for agricultural and pest control purposes.
Check Digit Verification of cas no
The CAS Registry Mumber 13043-66-8 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,3,0,4 and 3 respectively; the second part has 2 digits, 6 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 13043-66:
(7*1)+(6*3)+(5*0)+(4*4)+(3*3)+(2*6)+(1*6)=68
68 % 10 = 8
So 13043-66-8 is a valid CAS Registry Number.
InChI:InChI=1/C17H34O2/c1-4-7-8-9-10-11-12-13-14-15-16-17(18-5-2)19-6-3/h15-17H,4-14H2,1-3H3/b16-15-
13043-66-8Relevant academic research and scientific papers
Quigley, Brendan L.,Grubbs, Robert H.
, p. 501 - 506 (2014)
The Z-selective cross metathesis of allylic-substituted olefins is explored with recently developed ruthenium-based metathesis catalysts. The reaction proceeds with excellent stereoselectivity for the Z-isomer (typically >95%) and yields of up to 88% for a variety of allylic substituents. This includes the first synthesis of Z-α,β-unsaturated acetals by cross metathesis and their elaboration to Z-α,β-unsaturated aldehydes. In addition, the reaction is tolerant of a variety of cross partners, varying in functionality and steric profile.
Cumulated Ylides, XII. A Stereoselective Synthetic Method for (Z)-α,β-Unsaturated Aldehydes
Bestmann, Hans Juergen,Roth, Kurt,Ettlinger, Manfred
, p. 161 - 171 (2007/10/02)
(2-Ethoxyvinyl)triphenylphosphonium bromide (5) is converted with sodium amide into the corresponding phosphaallenylide 6 which adds ethanol forming the ylide 7. 7 is also obtained by the reaction of 5 with sodium ethanolate.The Wittig reaction of 7 with aldehydes 2 proceeds with high (Z)-stereoselectivity to give (Z)-α,β-unsaturated acetals 8 which are cleaved under well defined conditions with p-toluenesulfonic acid or with wet silica gel to (Z)-α,β-unsaturated aldehydes 9.
