(Z)-1,1-Diethoxytridec-2-ene

Base Information

• Chemical Name: (Z)-1,1-Diethoxytridec-2-ene
• CAS No.: 13043-66-8
• Molecular Formula: C17H34 O2
• Molecular Weight: 270.456
• Hs Code.: 2911000000
• European Community (EC) Number: 235-919-8
• DSSTox Substance ID: DTXSID301302585
• Nikkaji Number: J317.779C
• Mol file: 13043-66-8.mol

Synonyms:(Z)-1,1-Diethoxytridec-2-ene;13043-66-8;EINECS 235-919-8;(Z)-2-Tridecenal diethyl acetal;DTXSID301302585;2-Tridecene, 1,1-diethoxy-, (Z)-

Chemical Property of (Z)-1,1-Diethoxytridec-2-ene

Chemical Property:

• Vapor Pressure: 0.000233mmHg at 25°C
• Boiling Point: 335.4°Cat760mmHg
• Flash Point: 92.1°C
• PSA: 18.46000
• Density: 0.856g/cm³
• LogP: 5.47250
• XLogP3: 6.4
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 14
• Exact Mass: 270.255880323
• Heavy Atom Count: 19
• Complexity: 184

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCCCCCCCC=CC(OCC)OCC
• Isomeric SMILES: CCCCCCCCCC/C=C\C(OCC)OCC

Technology Process of (Z)-1,1-Diethoxytridec-2-ene

There total 4 articles about (Z)-1,1-Diethoxytridec-2-ene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 77.0%

undecylaldehyde (112-44-7) + (2,2-Diethoxyethyliden)triphenylphosphoran (71276-94-3) → 1,1-diethoxy-tridec-2c-ene (13043-66-8)

Guidance literature:

In diethyl ether; 1.) 0 deg C, 15 min, 2.) r.t., 3 h;

Reference yield: 70.0%

1-dodecene (112-41-4,25067-08-7,62132-67-6) + acrylaldehyde diethyl acetal (3054-95-3) → 1,1-diethoxy-tridec-2c-ene (13043-66-8)

Guidance literature:

With C₃₅H₄₅N₃O₄Ru; In tetrahydrofuran; at 35 ℃; for 3h; stereoselective reaction;

DOI:10.1039/c3sc52806e

Reference yield:

ethyl bromide (74-96-4) + ethanol (64-17-5) + undecylaldehyde (112-44-7) + (triphenylphosphoranylidene)acetaldehyde (2136-75-6) → 1,1-diethoxy-tridec-2c-ene (13043-66-8)

Guidance literature:

Multistep reaction;

upstream raw materials:

ethyl bromide

ethanol

undecylaldehyde

(triphenylphosphoranylidene)acetaldehyde

Downstream raw materials:

(2E)-tridecenal

tridec-2c-enal