130451-45-5

Upstream product

• 108-59-8 malonic acid dimethyl ester 
• 5949-05-3 (S)-Citronellal 
• 130451-44-4 2-((S)-3,7-Dimethyl-oct-6-enylidene)-malonic acid dimethyl ester 
• 2033-24-1 cycl-isopropylidene malonate 
• 106-23-0 3,7-dimethyl-oct-6-enal 
• 37517-81-0 3-chloro-3-oxopropanoic acid methyl ester 
• 70512-12-8 7-methyloct-6-enal 
• 140407-82-5 2-(3,7-Dimethyl-oct-6-enylidene)-malonic acid dimethyl ester 

Downstream Products

• 114032-15-4 [(1R,2S,5S)-2-(3-Hydroxy-1-methylene-propyl)-5-methyl-cyclohexyl]-acetic acid methyl ester 
• 114032-17-6 [(1R,2S,5S)-2-(3-Iodo-1-methylene-propyl)-5-methyl-cyclohexyl]-acetic acid methyl ester 
• 114032-16-5 {(1R,2S,5S)-5-Methyl-2-[1-methylene-3-(toluene-4-sulfonyloxy)-propyl]-cyclohexyl}-acetic acid methyl ester 
• 130451-46-6 Chlorocarbonyl-((1S,2S,5S)-2-isopropenyl-5-methyl-cyclohexyl)-acetic acid methyl ester 
• 130451-48-8 2-((1S,2S,5S)-2-Isopropenyl-5-methyl-cyclohexyl)-malonic acid monomethyl ester 

Relevant academic research and scientific papers

Stereoselective Festphasensynthese von Cyclopentanen und Cyclohexanen durch Mehrkomponenten-Domino-Reaktion - Aufbau einer Substanzbibliothek durch kombinatorische Chemie

Keywords: En-Reaktionen; Festphasensynthesen; Kaskadenreaktionen; Kombinatorische Chemie; Mehrkomponentenreaktionen

The Acid-Catalyzed Cyclization of Unsaturated Carbonyl Compounds Utilizing Silica Gel at High Pressure

The ene-like cyclizations of a series of unsaturated carbonyl compounds have been studied using silica gel at high pressure (15 kbar) as a new catalytic system.This new method is general for forming 5- and 6-membered ring carbocycles.The mildness of this

A new enantiospecific route to the pseudopterosins

An efficient and highly stereoselective process is described for the preparation of ketones 3 and 4, key compounds for the total synthesis of pseudopterosins such as 1 and 2.