130459-40-4

Upstream product

• 102614-19-7 (4S)-4-(2'-Oxoethyl)-2-phenyloxazoline 
• 1730-25-2 allylmagnesium bromide 
• 102614-13-1 2-phenyl-4(S)-<2-((2-methyl-2-propyl)thio)-2-oxoethyl>-2-oxazoline 
• 3052-45-7 allyllithium 

Downstream Products

• 171524-12-2 (3S,5S,8R,9R,11R)-1-(Benzyloxy)-3,5:9,11-di-O-isopropylidene-13-tetradecene-3,5,8,9,11-pentol 
• 171523-94-7 (2R,4'S)-N'-Benzyl-2-<oxy>-1-(4'-oxazolidinyl)-4-pentene 
• 171523-97-0 (2R,4R)-4-<oxy>-1-(phenylthio)-6-hepten-2-ol 
• 171523-98-1 (2R,4R)-2,4-O-Isopropylidene-1-(phenylthio)-6-heptene-2-ol 
• 171524-14-4 (3S,5S,8R,9R,11R)-1-(Benzyloxy)-3,5:9,11-di-O-isopropylidene-8-<oxy>-13-oxotridecane-3,5,9,11-tetrol 
• 171524-13-3 (3S,5S,8R,9R,11R)-1-(Benzyloxy)-3,5:9,11-di-O-isopropylidene-8-<oxy>-13-tetradecene-3,5,9,11-tetrol 
• 171524-10-0 (3S,5S,9R,11R)-1-(Benzyloxy)-3,5:9,11-di-O-isopropylidene-8-oxo-13-tetradecene-3,5,9,11-tetrol 
• 171524-06-4 (3S,5S)-7-(Benzyloxy)-3,5-O-isopropylidene-1-(phenylthio)heptane-3,5-diol 
• 171524-03-1 (3S,5R)-1-(Benzyloxy)-5-<oxy>-7-octen-3-ol 
• 171524-04-2 (4R,6S)-4-allyl-6-(2-(benzyloxy)ethyl)-2,2-dimethyl-1,3-dioxane 
• 171524-11-1 (3S,5S)-7-(Benzyloxy)-1-iodo-3,5-O-isopropylideneheptane-3,5-diol 
• 171599-00-1 2-{(4R,6S)-6-[2-(benzyloxy)ethyl]-2,2-dimethyl-1,3-dioxan-4-yl}ethanol 
• 130459-42-6 (2S,4R)-2-(N-Benzyl-N-methylamino)-4-<oxy>-6-hepten-1-ol 
• 171523-93-6 (2S,4R)-2-(N-Benzylamino)-4-<oxy>-6-hepten-1-ol 

Relevant academic research and scientific papers

Synthetic studies on the polyene macrolide antibiotics. Development of syn- and anti-1,3-diol subunits and assembly of the polyacetate region of amphotericin B

The synthesis of syn- and anti-1,3-diol subunits from thiol ester oxazoline 4 has been described. The key features of these synthetic sequences include the stereodivergent allylation of an asymmetric β-amino aldehyde (7) and the stereospecific transformat

Studies toward the application of oxazoline-epoxide equivalency in 1,3-asymmetric induction

Synthetically versatile epoxy alcohols have been prepared from a common intermediate, chiral aldehyde, through a sequence involving diastereoselective allylation followed by stereospecific transformation of the oxazoline to an epoxide.