130490-54-9Relevant articles and documents
Isomerization of alkynes to 1,3-dienes under rhodium or palladium catalysis
Yasui, Hiroto,Yorimitsu, Hideki,Oshima, Koichiro
, p. 1783 - 1785 (2006)
Treatment of 1-aryl-1-octyne with allyltributylstannane under rhodium catalysis provided 1-aryl-1,3-octadiene in good yield. A combination of ally1 acetate and a palladium catalyst also effected the isomerization of alkynes to 1,3-dienes. Georg Thieme Ver
3-Methoxy-1-(tributylstannyl)-1-propene, a versatile vinyltin synthon
Verlhac, Jean-Baptiste,Pereyre, Michel
, p. 283 - 288 (2007/10/02)
3-Methoxy-1-(tributylstannyl)-1-propene (1) can be readily transformed into the silylated analogue (2), which can react both as a vinyltin and as an allylsilane.Thus, transmetallation of 2 with n-butyllithium, followed by quenching with various electrophi
SYNTHESIS OF VINYL ETHERS BY HOMOLOGATION OF ALDEHYDES VIA RADICAL REDUCTIVE ELIMINATION
Vatele, Jean-Michel
, p. 5997 - 6000 (2007/10/02)
Methoxyphenylthiomethyllithium 1 reacts with aldehydes to give adducts which are then transformed into xanthates.These compounds, by reaction with tri-n-butylstannane, afford vinyl ethers in good yields.