130521-15-2

Basic information

• Product Name: (Z)-1-nitro-2-phenylthioethylene
• Synonyms: (Z)-1-nitro-2-phenylthioethylene
• CAS NO: 130521-15-2
• Molecular Weight: 181.215
• Mol File: 130521-15-2.mol

Chemical Properties

• CAS DataBase Reference: (Z)-1-nitro-2-phenylthioethylene(CAS DataBase Reference)
• NIST Chemistry Reference: (Z)-1-nitro-2-phenylthioethylene(130521-15-2)
• EPA Substance Registry System: (Z)-1-nitro-2-phenylthioethylene(130521-15-2)

Safety Data

• Hazardous Substances Data: 130521-15-2(Hazardous Substances Data)

Upstream product

• 1822-73-7 phenylthioethylene 
• 18942-89-7 2-nitroethyl acetate 
• 108-98-5 thiophenol 

Relevant articles and documents

A selective and practical synthesis of nitroolefins

A straightforward and general synthesis of nitroolefins from nitric oxide (NO) and olefins is presented. The direct nitration of aromatic olefins, allyl compounds, and acrylic acid derivatives proceeds smoothly at room temperature with high regioselectivity and good yields. The advantages of this novel procedure compared to established nitration procedures are demonstrated.

STEREOCHEMISTRY OF THE THIYLATION OF 1,2-DINITROALKENES AND 1,4-DINITRO-1,3-DIENES

In thiylation with arenethiolates 1,2-dinitroalkenes form 1-nitro-2-arylthioalkenes in the more stable Z form, and in the absence of a base they form a mixture of the Z and E isomers.During thiylation with arenethiols 1,4-dinitro-1,3-butadienes only give (E,E)-1-nitro-4-arylthio-1,3-dienes.