130523-98-7

Upstream product

• 131613-82-6 (2S,4aR,6S,7R,8S,8aS)-7,8-bis(benzyloxy)-6-methoxy-2-(4-methoxyphenyl)hexahydropyrano[3,2-d][1,3]dioxine 
• 94827-31-3 methyl 2,3-di-O-benzyl-4-O-(4-methoxybenzyl)-α-D-galactopyranoside 
• 161443-23-8 methyl 2,3-di-O-benzyl-4,6-O-(4-methoxybenzylidene)-α-D-glucopyranoside 
• 90633-88-8 methyl-2,3-bis-O-benzyl-4,6-O-[(R)-(4-methoxyphenyl)methylene]-α-D-glucopyranoside 
• 97-30-3 methyl-alpha-D-glucopyranoside 
• 100-39-0 benzyl bromide 
• 2186-92-7 p-Anisaldehyde dimethyl acetal 
• 18929-63-0 methyl 4,6-O-para-methoxybenzylidene-α-D-glucopyranoside 
• 90633-95-7 methyl 2,3-bis-O-benzyl-4-O-[(4-methoxyphenyl)methyl]-α-D-glucopyranoside 
• 161443-22-7 methyl 4,6-O-(4-methoxybenzylidene)-α-D-glucopyranoside 

Downstream Products

• 130523-99-8 methyl 2,3-di-O-benzyl-7,8,9-trideoxy-4-O-(4-methoxybenzyl)-D-glycero-α-D-gluco-non-8-enopyranoside 
• 130524-00-4 methyl 2,3-di-O-benzyl-7,8,9-trideoxy-4-O-(4-methoxybenzyl)-L-glycero-α-D-gluco-non-8-enopyranoside 
• 202338-72-5 (E)-3-[(2R,3R,4S,5R,6S)-4,5-Bis-benzyloxy-6-methoxy-3-(4-methoxy-benzyloxy)-tetrahydro-pyran-2-yl]-acrylic acid methyl ester 
• 236424-91-2 methyl 2,3-di-O-benzyl-6,7-dideoxy-4-O-(4-methoxybenzyl)-α-D-gluco-hept-6-enopyranoside 
• 273926-03-7 (2S,3R,4S,5R,6R)-3,4-Bis-benzyloxy-6-ethynyl-2-methoxy-5-(4-methoxy-benzyloxy)-tetrahydro-pyran 
• 161364-91-6 (1S,2R,3S,4S,5R,6R)-4,5-Bis-benzyloxy-6-(4-methoxy-benzyloxy)-cyclohexane-1,2,3-triol 
• 131529-73-2 ethyl uronate 
• 131529-74-3 methyl (E)-2,3-di-O-benzyl-6,7-dideoxy-4-O-(4-methoxybenzyl)α-D-galacto-oct-6-enedialdo-1,5-pyranoside 
• 131548-59-9 (2S,3R,4S,5S,6R)-3,4-Bis-benzyloxy-6-((E)-3-chloro-propenyl)-2-methoxy-5-(4-methoxy-benzyloxy)-tetrahydro-pyran 
• 131529-30-1 methyl (E)-2,3-di-O-benzyl-6,7-dideoxy-4-O-(4-methoxybenzyl)-α-D-galacto-oct-6-enoside 
• 131529-70-9 methyl (E)-2,3-di-O-benzyl-6,7,8-trideoxy-4-O-(4-methoxybenzyl)-α-D-galacto-oct-6-enoside 
• 124780-66-1 methyl (E)-2,3-di-O-benzyl-6,7,8-trideoxy-α-D-galacto-oct-6-enopyranoside 
• 131529-72-1 ethyl uronate 
• 131529-71-0 methyl (Z)-2,3-di-O-benzyl-6,7,8-trideoxy-4-O-(4-methoxybenzyl)-α-D-galacto-oct-6-enoside 

Relevant academic research and scientific papers

Radical cyclization of sugar-derived β-(alkynyloxy)acrylates: Synthesis of novel fused ethers

(equation presented) Tributyltin radical mediated cyclization of carbohydrate-derived β-(alkynyloxy)acrylates leading to highly functionalized cis-and trans-fused bicyclic ethers of various ring sizes is described. The efficacy of the radical cyclization is nicely illustrated in the iterative construction of a frans-fused tricyclic tetrahydropyran.

A convenient route to cis- and trans-fused bicyclic ethers by ruthenium mediated ring-closing metathesis of diene and enyne carbohydrate derivatives

A general approach towards the construction of highly functionalised pyranopyran and pyranofuran systems via Grubbs [Ru] catalysed ring-closing metatheses of neighbouring vinyl-O-allyl and vinyl-O-propargyl functions on monosaccharide scaffolds is describ

Synthesis of L-α-phosphatidyl-D-myo-inositoi 5-phosphate and L-α- phosphatidyl-D-myo-inositol 3,5-bisphosphate

Two new 5-phosphorylated phosphatidylinositols have been synthesized from methyl α-D-glucopyranoside as the chiral precursor. These new PtdInsP(n)s have been recently detected in mammalian cells.

Chiral Synthesis of the BC-Ring System of Ciguatoxin from D-Glucose

The BC-ring system of ciguatoxin was stereoselectively synthesized by 12 steps from methyl α-D-glucopyranoside.

Synthesis of P-5 tethered inositol-1,2,6-trisphosphate, an affinity reagent for α-trinositol receptors

The synthesis of D-myo-P-5-(O-aminopropyl)-Ins(1,2,5,6)P4, a phosphodiester analog of Ins(1,2,6)P3 tethered at the C-5 position, has been achieved and a photoaffinity label has been prepared.

STEREOSELECTIVE SYNTHESIS OF DIPYRANYL C-DISACCHARIDES

The synthesis of trans-fused dipyranyl sugars containing an acetylenic moiety at C-1 has been completed starting from D-glucose.Formation of the β-substituted C-disaccharide provides a water soluble sugar-based linker spanning approximately 12.8 Angstroem.

Synthesis and enzymatic evaluation of two conformationally restricted trisaccharide analogues as substrates for N-acetylglucosaminyltransferase V

The synthetic trisaccharide βGlcNAc(1→2)αMan(1→6)βGlc-O(CH2) 7CH3 (5) is an acceptor substrate for the enzyme N-acetylglucosaminyltransferase V (GlcNAcT-V) which adds an additional βGlcNAc residue to the 6-position of the

Preferred Conformation of C-Glycosides. 7. Preferred Conformation of Carbon Analogues of Isomaltose and Gentiobiose

The preferred solution conformation of the 1,6-linked C-disaccharides 3 and 4, carbon analogues of methyl isomaltoside and methyl gentiobioside, was shown to be 3-A and 4-A, respectively, by 1H NMR spectroscopy.

The Synthesis of Some Octenoses as Potential Precursors to Lincosamine, a Derived Portion of the Antibiotic Lincomycin

Methyl (E)-2,3-di-O-benzyl-6,7,8-trideoxy-α-D-galacto-oct-6-enopyranoside, a potential precursor to lincosamine, has been prepared from both methyl α-D-galactopyranoside and methyl α-D-glucopyranoside, with the required inversion at C4 in the latter sequence being effected by a conventional oxidation-reduction.As well, (E)-6,7-dideoxy-1,2:3,4-di-O-isopropylidene-α-D-galacto-oct-6-enose and (E)- and (Z)-6,7,8-trideoxy-1,2:3,4-di-O-isopropylidene-α-D-galacto-oct-6-enose have been prepared from 1,2:3,4-di-O-isopropylidene-α-D-galactose.