130534-91-7

Basic information

• Product Name: Benzene, 1-bromo-4-[(methoxymethoxy)methyl]-
• CAS NO: 130534-91-7
• Molecular Formula: C9H11BrO2
• Molecular Weight: 231.089
• Mol File: 130534-91-7.mol
• Article Data: 15

Chemical Properties

• CAS DataBase Reference: Benzene, 1-bromo-4-[(methoxymethoxy)methyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-bromo-4-[(methoxymethoxy)methyl]-(130534-91-7)
• EPA Substance Registry System: Benzene, 1-bromo-4-[(methoxymethoxy)methyl]-(130534-91-7)

Safety Data

• Hazardous Substances Data: 130534-91-7(Hazardous Substances Data)

Upstream product

• 873-75-6 4-bromobenzenemethanol 
• 109-87-5 Dimethoxymethane 
• 107-30-2 chloromethyl methyl ether 

Downstream Products

• 130534-92-8 2,2,2-Trifluoro-1-(4-methoxymethoxymethyl-phenyl)-ethanone 
• 329767-69-3 1,4-anhydro-2-deoxy-1-C-[4-(hydroxymethyl)phenyl]-3,5-O-[1,1,3,3-tetrakis(1-methylethyl)-1,3-disiloxanediyl]-D-erythro-pentitol 
• 404567-13-1 1,4-anhydro-2-deoxy-1-C-[4-[(methoxymethoxy)methyl]phenyl]-3,5-O-[1,1,3,3-tetrakis(1-methylethyl)-1,3-disiloxanediyl]-D-erythro-pentitol 
• 404567-14-2 1,4-anhydro-2-deoxy-1-C-[4-[[2-[2-[[4-[(1E)-2-phenylethenyl]phenyl]methoxy]ethoxy]ethoxy]methyl]phenyl]-D-erythro-pentitol 
• 329767-70-6 1,4-anhydro-2-deoxy-1-C-[4-[[2-[2-[[4-[(1E)-2-phenylethenyl]phenyl]methoxy]ethoxy]ethoxy]methyl]phenyl]-3,5-O-[1,1,3,3-tetrakis(1-methylethyl)-1,3-disiloxanediyl]-D-erythro-pentitol 
• 454678-93-4 2-{4-[(methoxymethyloxy)methyl]phenyl}thiazole 
• 454678-91-2 (4-(thiazol-2-yl)phenyl)methanol 
• 1392440-51-5 C₁₄H₁₆O₂S 
• 86605-93-8 (4-bromobenzyloxy)trimethylsilane 
• 21388-92-1 4-bromobenzyl acetate 
• 589-15-1 1-bromomethyl-4-bromobenzene 
• 55883-45-9 4-bromobenzyliodide 
• 16532-79-9 4-Bromophenylacetonitrile 
• 873-75-6 4-bromobenzenemethanol 

Relevant articles and documents

Metal hydrogen sulfates catalyzed methoxymethylation of alcohols under solvent-free conditions

Methoxymethylation of a variety of alcohols was performed by using formaldehyde dimethoxy acetal in the presence of metal hydrogen sulfate M(HSO4)n at room temperature and solvent-free conditions. The methoxymethyl ethers (MOM-ethers

BiCl3-Facilitated removal of methoxymethyl-ether/ester derivatives and DFT study of -O-C-O- bond cleavage

A simple method for the cleavage of methoxymethyl (MOM)-ether and ester derivatives using bismuth trichloride (BiCl3) is described. The alkyl, alkenyl, alkynyl, benzyl and anthracene MOM ether derivatives, as well as MOM esters of both aliphatic and aromatic carboxylic acids, were deprotected in good yields. To better understand the molecular roles of BiCl3and water for MOM cleavage, two possible binding pathways were investigated using the density functional theory (DFT) method. The theoretical results indicate the differential initial binding site preferences of phenolic and alcoholic MOM substrates to the Bi atom and suggest that water plays a key role in facilitating the cleavage of the MOM group.

H3PW12O40at the[bmim][FeCl4]: A green catalytic system for alkoxymethylation of alcohols and their one-pot interconversion to acetates and TMS-ethers

12-Tungstophosphoric acid immobilized on [bmim][FeCl4] was found to be an efficient catalyst for chemoselective methoxymethylation and ethxoymethylation of alcohols and also one-pot conversion of MOM- or EOM-ethers to their corresponding acetates and TMS-ethers under thermal conditions and microwave irradiation. These procedures were simple, rapid and the corresponding products were obtained in high yields. The catalyst exhibited remarkable reactivity and was reusable.

Highly efficient and selective methoxymethylation of alcohols and phenols catalyzed by high-valent tin(IV) porphyrin

An efficient and selective method for methoxymethylation of alcohols and phenols with formaldehyde dimethyl acetal (FDMA) catalyzed by electron deficient tin(IV)tetraphenylporphyrinato trifluoromethanesulfonate, [SnIV(TPP)(OTf)2], is