130537-95-0Relevant academic research and scientific papers
INTRAMOLECULAR CYCLIZATION OF 2'-OLEFINIC SIDE-CHAINS ON ANODICALLY OXIDIZED 4-PHENYLPHENOLS. THE EFFECT OF OLEFIN SUBSTITUENTS ON CARBON-CARBON BOND FORMATION
Morrow, Gary W.,Chen, Ying,Swenton, John S.
, p. 655 - 664 (2007/10/02)
The anodic oxidation of 4-(2'-alkenylphenyl)phenols in acetonitrile/methanol affords spirodienones arising from cyclization of the olefinic side-chain to the 4-position of the phenol and reaction of the resulting benzylic cation with methanol.The efficiency of this carbon-carbon bond-forming reaction is dependent upon the olefinic substituents.
Spiro-annulated 2,5-cyclohexadienones via oxidation of 2'-alkenyl-p-phenyl phenols with iodobenzene diacetate
Callinan,Chen,Morrow,Swenton
, p. 4551 - 4552 (2007/10/02)
The oxidation of 2-alkenyl-substituted p-phenyl phenols via iodobenzene diacetate gives spiro-annulated-2,5-cyclohexadienones.
